Got this information from another forum-http://www.spainexpat.com/spain/forum/viewthread/2791/
First it wasn’t nearly as confusing or as slow as it seemed it would be so take heart Although, it does take time and you get to see a lot of the city…
Second, for non-EU family members of EU citizens it’s one form for both NIE & Tarjeta de residencia.
Our situation is: I’m from Australia and married a Spaniard, here in Spain, this year. (My 90 day Schengen visa had already expired and I was advised by a lawyer this was not a problem once we submitted the marriage papers as long as I didn’t travel).
Step one was to make an appointment with the Oficina de Extranjeria. I got one (in Barcelona) for about a week after the wedding.
Note:
1) you can’t request the appointment until after you are actually married
2) get there early as you have to take a number in order to wait to take a 2nd number in order to have your appointment (!!)
3) make at least two copies of everything
4) The office in Barcelona has moved to C/ Murcia 42 (Metro Navas)
I had to present the following:
- a completed EX-16 form (Solicitud de Certificado de registro como residente comunitaria o Tarjeta de residencia de familiar de ciudadano de la Union) + copies
- Libro de Familia + copy
- my passport + copy
- my husband’s ORIGINAL DNI card + copy
- my certificado de empadronamiento
Note: Before going we were told we needed our literal marriage certificate (Certificado literal de matrimonio) but I hadn’t received that yet and it wasn’t a problem.
At the Oficina de Extranjeria they stamped my EX-16 form and gave me a letter stating a date after which I could go to the Comisaria de Policia. The date was approximately one month later.
Step two at the Policia I had to present:
- the letter from the Oficina de Extranjeria
- my stamped EX-16
- my passport
- 2 passport photos
- my certificado de empadronamiento (this needs to be less than 3 months old)
They take your fingerprints and give you a “Resguardoâ€